ThuliumV1, Main, Exploration, bibRecord, 001615

Observation and interpretation of the Tm3+ free ion spectrum

Identifieur interne : 001615 ( Main/Exploration ); précédent : 001614; suivant : 001616

Observation and interpretation of the Tm3+ free ion spectrum

Auteurs : A. Meftah [France] ; J.-F. Wyart [France] ; N. Champion [France] ; W.-U. L. Tchang-Brillet [France]

Source :

The European physical journal. D, Atomic, molecular and optical physics [ 1434-6060 ] ; 2007.

RBID : Pascal:07-0460039

Descripteurs français

Pascal (Inist)
- Interaction configuration, Spectre émission, Niveau énergie, Thulium Ion atomique, Ion positif, Ion multichargé, Probabilité transition, 3115M, Tm ip 3, 3270C.

English descriptors

KwdEn :
- Configuration interaction, Emission spectra, Energy levels, Multicharged ions, Positive ions, Thulium Atomic ions, Transition probabilities.

Abstract

The emission spectrum of thulium produced by a vacuum spark source was observed in the wavelength range from 700 to 2320 Å on the 10.7 m normal-incidence vacuum ultraviolet spectrograph at the Paris-Meudon observatory. In the unknown spectrum of Tm IV, more than 760 lines have been identified for the first time as transitions between 157 levels of 4f¹¹5d, 33 levels of 4f¹¹6p, 9 levels of 4f¹¹6s and 10 levels of the 4f¹² ground configuration. A parametric interpretation of the levels has been carried out using the Cowan codes. Configuration interaction effects are discussed, in particular with the core-excited configurations 5p⁵4f¹³ and 5p⁵4f¹²5d. Radial Slater parameters derived from 4f¹² levels are larger than those pertaining to trivalent Tm ions in compounds. A selection of 105 prominent lines is given.

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Pascal, to step Corpus: 000725
to stream Pascal, to step Curation: 000725
to stream Pascal, to step Checkpoint: 000753
to stream Main, to step Merge: 001663
to stream Main, to step Curation: 001615

Le document en format XML

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<term>Transition probabilities</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>Interaction configuration</term>
<term>Spectre émission</term>
<term>Niveau énergie</term>
<term>Thulium Ion atomique</term>
<term>Ion positif</term>
<term>Ion multichargé</term>
<term>Probabilité transition</term>
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<front><div type="abstract" xml:lang="en">The emission spectrum of thulium produced by a vacuum spark source was observed in the wavelength range from 700 to 2320 Å on the 10.7 m normal-incidence vacuum ultraviolet spectrograph at the Paris-Meudon observatory. In the unknown spectrum of Tm IV, more than 760 lines have been identified for the first time as transitions between 157 levels of 4f<sup>11</sup>
5d, 33 levels of 4f<sup>11</sup>
6p, 9 levels of 4f<sup>11</sup>
6s and 10 levels of the 4f<sup>12</sup>
 ground configuration. A parametric interpretation of the levels has been carried out using the Cowan codes. Configuration interaction effects are discussed, in particular with the core-excited configurations 5p<sup>5</sup>
4f<sup>13</sup>
 and 5p<sup>5</sup>
4f<sup>12</sup>
5d. Radial Slater parameters derived from 4f<sup>12</sup>
 levels are larger than those pertaining to trivalent Tm ions in compounds. A selection of 105 prominent lines is given.</div>
</front>
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Observation and interpretation of the Tm3+ free ion spectrum

Observation and interpretation of the Tm3+ free ion spectrum

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri